Si Jiahui is from Zhuji, Shaoxing. He lives in the United Kingdom. At age 12, Si Jiahui began training at the Wiraka Billiard Academy in Foshan.
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At 14, Si Jiahui defeated former world number one Ding Junhui 3–2 in a national tournament.

Playing in the 2021 UK Championship as an amateur competitor, Si Jiahui defeated former world champion Shaun Murphy 6–5 in the first round. Si won the 2022 World Snooker Federation Open, defeating Lee Stephens 5–0 in the final.
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At the 2022 European Masters, Si Jiahui defeated Anthony McGill and Daniel Wells to reach his first quarter-final at a ranking event.
Si Jiahui was ranked 80th in the world rankings and qualified for the main stage of the 2023 World Snooker Championship after defeating Florian Nüßle, Tom Ford, and Jordan Brown in the qualifying rounds.
In the first round at the Crucible Theatre, Si Jiahui defeated Murphy 10–9. Si Jiahui became the youngest player to reach the World Championship semi-finals since Ronnie O’Sullivan in 1996.


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